Assuming publicly-traded security owned for more than a year.
Yes, you should ensure it goes on Part I of the 8232. 30% of AGI limitation applies. There's no sale on the 1099-B, because your guy didn't sell anything. FMV is the average of the high and low on the donation date; don't assume the acknowledgement letter uses the correct value.
FYI - It goes with the $5,000 OR LESS donations, if it is publicly traded.
From the instructions for 8283:
Use Section A to report donations of property for which
you claimed a deduction of $5,000 or less per item or
group of similar items (defined later). Also use Section A
to report donations of publicly traded securities;
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