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Unfortunately, you can't turn that on as an administrator because the Intuit accounts your team members use to log in are owned and managed by each individual. Manage Users merely creates a connection between your account and these individuals and assigns a certain level of access rights to each.
2FA must be turned on by each individual user at https://accounts.intuit.com. Changes made here will affect not only their access to Lacerte under your account but also their access to other Intuit products associated with that particular email address.